Design, synthesis and optical properties of unsymmetrical subphthalocyanine trimer connected by phloroglucinol via axial positions.
نویسندگان
چکیده
An unsymmetrical subphthalocyanine trimer consisting of three different subphthalocyanine units was synthesized. Its optical and physical properties were investigated by UV/Vis, fluorescence spectrometry, cyclic voltammetry and computations. Energy transfer from the non-substituted subphthalocyanine unit to the perfluorinated subphthalocyanine unit via a trifluoroethoxy substituted unit is suggested.
منابع مشابه
Synthesis and Photosensitizing Properties of an Activatable Phthalocyanine-Subphthalocyanine Triad
In this article, we describe a photosensitizer (PS) whose ability to generate singlet oxygen (1O2) and fluorescence emission has been designed as tumor responsive. More specifically, the PS consists of a silicon phthalocyanine (SiPc) core, axially substituted with two subphthalocyanine (SubPc) units, covalently linked by a disulfide linker, which is cleavable in the presence of a strong reducin...
متن کاملOptimization mechanical properties of polyurethane/Sio2 nanocomposite on Polypropylene substrate for automotive clear coating by Taguchi method
The effect of different parameters including: nano silica content, curing temperature, type of hardener, and flash-off time on mechanical and optical properties of polyurethane PU based clearcoat was investigated via standard Taguchi L9 method. Dispersion of nano silica in the resultant nanocomposites was explored by scanning electron microscopy SEM. SEM images showed a fine dispersion through ...
متن کاملBi-functional NaLuF4:Gd3+/Yb3+/Er3+ nanocrystals: hydrothermal synthesis, optical and magnetic properties
Magnetic-fluorescent lanthanide doped sodium lutetium fluoride (NaLuF4:Yb3+/Er3+/Gd3+) nanocrystals were synthesized via facile hydrothermal method by varying concentration of Gd3+. Powder X-ray powder diffraction (PXRD), scanning electron microscopy (SEM),transmission electron microscopy (TEM), energy dispersive X-ray spectroscopy (EDS), p...
متن کاملIntegration of inherent and induced chirality into subphthalocyanine analogue
Conventional conjugated systems are characteristic of only either inherent or induced chirality because of synthetic challenge in combination of chiral segment into the main chromophore. In this work, chiral binaphthyl segment is directly fused into the central chromophore of a subphthalocyanine skeleton, resulting in a novel type of chiral subphthalocyanine analogue (R/S)-1 of integrated inher...
متن کاملSynthesis and Characterization of Metal Complexes with New Unsymmetrical Schiff Base Ligand Derived from 2-Aminoethanethiol
A new unsymmetric thioether diamine N - ( 2 - ( 2 - aminophenylthio) ethyl) benzene - 1 , 2 - diamine was prepared through the nucleophilic substitution of cysteaminium chloride with 1 - chloro - 2 - nitrobenzene and then the nitro groups of prepared compuond converted to the amine by zinc powder and ammonium chloride. Then, unsymmetric Schiff bass ligand 2 - ((( 2 - (( 2 - (( 2 - (( 2 - hydrox...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- Dalton transactions
دوره 45 3 شماره
صفحات -
تاریخ انتشار 2016